DOI: 10.17151/10.17151/luaz.2015.40.3
How to Cite
Medina Villadiego, M., Ospino Roa, Y., & Tejeda Benítez, L. (2015). Esterification and transesterification of waste oils for biodiesel obtaining. Luna Azul, (40), 25–34. https://doi.org/10.17151/10.17151/luaz.2015.40.3

Authors

Mauricio Medina Villadiego
Universidad de Cartagena
maume12@hotmail.com
Yesid Ospino Roa
Universidad de Cartagena
yesi_or1025@hotmail.com
Lesly Tejeda Benítez
Universidad de Cartagena
lptbenitez@gmail.com

Abstract

Biodiesel is a biofuel produced from fats and oils and because of the disadvantages of fossil oils use, its production and consumption has increased in recent years. In this work the esterification of waste oil by acid catalysis and alkaline transesterification to obtain biodiesel was studied. The oil-methanol (6:1 and 5:1) ratio conditions and catalyst concentration were varied to select the most favorable for the process. The oils used were collected in restaurants in the city of Cartagena. It was found that the variable to greater effect on the reaction yield was the oil-methanol ratio, favoring low concentrations of methanol (6:1), from which yields higher than 93% are obtained. The catalyst concentration did not affect significantly the efficiency of
esterification. The biodiesel obtained had good acidity characteristics and low sulfur content. Additionally the need for a pretreatment to oils and biodiesel purification to achieve compliance of international standards was evidenced.

Aroua, M.K., Atadashi, I.M. y Aziz, A. A. (2010). High quality biodiesel and its diesel engine application: A review. Renewable and
sustainable energy review, 14(7), 1999-2008.

Basha, S.A., Gopal, K.R. y Jebaraj, S. (2009). A review on biodiesel production, combustion, emissions and performance. Renewable and
sustainable energy reviews, 13(6-7), 1628-1634.

Berkemeier, R., Bordado, J., Correia, M., Felizardo, P., Mendes, J. y Raposo, I. (2006). Production of biodiesel from waste frying waste
frying oil. Waste Manage, 26(5), 487-494.

Chen, S., Yan, Y., Yang, R. y Zhang, J. (2010). Biodiesel production from vegetable oil using heterogeneous acid and alkali catalyst. Fuel,
89(10), 2939-2944.

Demirbas, A. (2009). Progress and recent trends in biodiesel fuels. Energy Conversion and Management, 50 (1), 14-34.

Deng, S., Lammers, P., Patil, P. y Rhodes, J. (2010). Conversion of waste cooking oil to biodiesel using ferric sulfate and supercritical
methanol processes. Fuel, 89(2), 360-364.

Enweremadu, C. y Mbarawa, M. (2009). Technical aspects of production and analysis of biodiesel from used cooking oil - A review.
Renewable and Sustainable Energy Reviews, 13(9), 2205-2224.

Gaffney, J. y Marley, N. (2009). The impacts of combustion emissions on air quality and climate - From coal to biofuels and
beyond. Atmospheric Environment, 43(1), 23-36.

Gumus, M. (2010). A comprehensive experimental investigation of combustion and heat release characteristics of a biodiesel (hazelnut
kernel oil methyl ester) fueled direct injection compression ignition engine. Fuel, 89(10), 2802-2814.

Hilbert, J., Lamersa, P. y McCormicka, K. (2008). The emerging liquid biofuel market in Argentina: Implications for domestic demand
and international trade. Energy Policy, 36(4), 1479-1490.

Kuang, L., Ma, S., Nie, J., Riley, W., Wang, Y. y Zhao, M. (2011). Improving the cold flow properties of biodiesel from waste cooking oil
by surfactants and detergent fractionation. Fuel, 90(3), 1036-1040.

Liu, S., McDonald, T. y Wang, Y. (2010). Producing biodiesel from high free fatty acids waste cooking oil assisted by radio frequency
heating. Fuel, 89(10), 2735-2740.

Phan, A. y Phan, T. (2008). Biodiesel production from waste cooking oils. Fuel, 87(17-18),3490-3496.

Sharma, Y., Singh, B. y Upadhyay, S. (2008). Advancements in development and characterization. Fuel, 87(12), 2355-2373.

Downloads

Download data is not yet available.
Sistema OJS - Metabiblioteca |